The rate constants of protonation of these reactants had been measured previously by manual analysis and their pK values are directly measured. |
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Thus, in order to calculate the vibrational frequencies and the rotational constants of a molecule all that is is needed is the input. |
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For example, maybe you really hate typing underscore characters, so you don't use them when naming database tables or named constants. |
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We determined the dissociation constants of our mutants for skeletal muscle actin using capped filaments. |
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In just a few of them the constants have taken on the right values for the creation of stars, life and evolution. |
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The rate constants are transformed to a logarithmic scale to ensure an even distribution over the large search space. |
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These phenomena ultimately depend on the molecular association and dissociation rate constants. |
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Similar picosecond time constants and spectral signatures have been observed for the cooling of a number of dye molecules including azobenzene. |
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Broadly speaking, technophobia, misguided technophilia, and dysfunctional bodies and relationships emerged as thematic constants. |
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The bimolecular rate constants for these reactions are of several orders of magnitude less than diffusion controlled. |
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Some of these constants, such as the fine-structure constant, are dimensionless and are not expressed in terms of units. |
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Bond distances, angles, and dihedrals, as well as the force constants, were taken for analogy with amino acids having similar functional groups. |
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The constants used were the mean values for H and J calculated from each set of field observations. |
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Dielectric constants of polar solvents are dominated by reorientation of their permanent dipoles. |
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They have measured the second-order electron transfer rate constants for reactions of dopa and c-dopa melanins with various radicals. |
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Hardcoded types are to generic code what magic constants are to regular code. |
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Stability constants of organic chelates on mineral or metal surfaces are thought to approximate levels measured by solution chemistry. |
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Their moral code is based on the idea that right and wrong are constants and that those who disagree are by definition immoral. |
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The spring constants had a small amount of heterogeneity, and the entire network was prestressed. |
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The open time constants are invariant to ligand concentrations, suggesting that ligand binds exclusively to the closed channel. |
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In general the dimension of rate constants strictly follows from the molecularity of the elementary reaction which they describe. |
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Pope John's canonization should help to illuminate the constants in his spiritual journey. |
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Finally, we have already mentioned that the use of different values of ionization constants led to the obtention of different values. |
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His comedy is a comedy of physics filled with precise formulas for directional qualities, but without standardized parameters or constants. |
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The story couldn't be convincingly told if there wasn't a convincing constructed context where there are constants, ephemera, characters, events, themes, boundaries, and plot. |
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Thus, to interpret the values, some effective temperature must be chosen and this is accomplished by calibrating the force constants to some known property. |
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For logical constants and their logicality see the entry on logical constants. |
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The proposals for demarcating logical constants that we have examined so far have all been analytical demarcations. |
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Support for RDF is basic rather than strict, so nearly all the URIs and URLs can be made up on the spot, as though they were variables or constants. |
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The fundamental constants are an extensive set of invariable quantities, such as the charge of the electron, which scientists use to predict a very wide range of phenomena. |
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The increment and decrement operators can be used only with variables, not with constants. |
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Common insulators such as glass or porcelain have constants raging from four to nine. |
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Therefore, the two growth constants, isochronous growth levels and simultaneous secretion across shared zooidal boundaries, apply to primary cystiphragm-cortex units. |
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Other constants also emerge: the miscues that sometimes occur in interprofessional collaboration and clinical and administrative support. |
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It maintains the optimal inspiratory time and automatically adjusts to changes in time constants during spontaneous breathing. |
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The constants A and B are specific to each oscillator and are estimated by measuring the period of fluids of known density. |
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But they do have to answer for that. One can tell a lot from a thinker's constants and variables. |
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But with each new challenge I am learning to embrace change as one of life's and business's constants. |
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Two visions of foreign policy oppose one another in this final leg of the electoral campaign, though some constants remain. |
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In everyday life and for leisure: find unexpected results, look for constants in series of situations or events. |
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Many of these constants must simply be observed empirically. |
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The first declaration is for the vector constants stored in cVals, sVals, iVals and fVals where the vector data type is declared and defined in the same statement. |
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The bimolecular quenching rate constants are less than that of diffusion controlled and decrease as the one-electron reduction potential of the donor radical increases. |
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Regardless of whether the scene is set in the seventeenth, eighteenth, or early nineteenth century prosperity and abundance are constants in these images. |
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The repartition of the two dyes in the final image corresponds with the expected one and the time constants retrieved are in good agreement with literature values. |
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Moreover, some controversy exists about the use of microscopic or macroscopic constants to calculate the relative concentration of each microspecies. |
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The first six constants are useful for calculating the actual size of a list box area in a form. |
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Dielectric constants of nonpolar solvents arise from induced dipoles. |
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The strong and weak nuclear coupling constants decrease with energy. |
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Values for the three unknown rate constants of the model are chosen such that a satisfactory concordance is achieved between simulated and observed psi and phi signals. |
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By contrast, non-singular or plural logic possesses singular and non-singular constants and variables. |
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The software minimizes the spatial error arising from the tilting movements and, at the end of the measurement process, automatically saves the machine geometry in the respective machine constants of the kinematics table. |
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The time constants that control one-shot pulse widths can be lengthened or shortened by adding capacitors or resistors in the test fixture. |
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Although these are constants, they are associated with the statistical behavior of populations of atoms. |
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For the anisotropic material, it requires the mathematics of a second order tensor and up to 21 material property constants. |
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The above expressions for the various equilibrium constants depend only on the concentrations of the species concerned, which are tacitly assumed to exist in solution independently of one another. |
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He's one of life's constants, like death and taxes, I noted loftily. |
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The let statement assigns a value to a variable, the right side of the equal sign being either a single variable or constant, or an arithmetic operation combining two variables or constants. |
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The divergences, the lack of foresight and the delays are the constants, which in this period, are witness to the lacunae of the European Community. |
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This document summarizes the models, constants and procedures used for data analysis in the IERS, and for the astrometry-geodesy community at large. |
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The hero visigodo Wulfric live in Segovia with his beautiful manacles hispanorromana, treating to put order in a Hispania sumida in the chaos by the constants oleadas bárbaras and the fault of government. |
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Bruce Schneier, a cryptographer and security commentator, frets that the NSA may have picked those constants so as to make the resulting codes vulnerable to decryption. |
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At its meeting in March 2007, the CCM identified a number of preparative steps towards a redefinition of the kilogram in terms of fundamental or atomic constants. |
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However, this free version does some basic operations, trigonometric functions, a unit converter, constants, and finds perimeters, areas, and volumes of geometric objects. |
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The form of a linguistic representation, basically, was what was left once we abstract from or ignore the representational features of everything except what we keep fixed, the logical constants. |
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Logic and algorithms Polynomial time algorithms based on monadic second-order logic and graph decompositions of bounded width, as discussed above, are not implementable directly due to the huge associated constants. |
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The ionised species have a low solubility, thus accurate determination of the two macro-dissociation constants by potentiometric titration has not been possible. |
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This allowed us to measure whole tri-dimensional astroids, which is important in order to find the magnetic anisotropy constants from the measured astroids. |
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Identifying constants in the domain of variation and signs of repetitivity in the kingdom of the irreproducible is the usual discourse of the physicist. |
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The values in SI units of all units in this table, except the astronomical unit, are taken from the 2002 CODATA set of recommended values of the fundamental physical constants, P. J. Mohr and B. N. Taylor, Rev. |
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But it also allows for the revelation of some constants or variations, as seen in Luxembourg with the majorettes, the soldiers, the swimmers, the footballers, the horseback riders, the choir singers and the employees. |
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Using denial any approach to proof-theoretic semantics can be dualized by just exchanging assertion and denial and turning from logical constants to their duals. |
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But we would then be explicating the notion of a logical constant in terms of an obscure primitive notion of logical necessity which we could not, on pain of circularity, explicate by reference to logical constants. |
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Its legitimacy, which relies on the double foundation of the people and of the member states, is reflected in bicameralism, which is one of the constants of federations. |
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The coupling constants are in general complex, in which case the Hamiltonians violate T-invariance. |
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He collaborated in efforts to form diamonds artificially, studied the pyroelectric properties of crystals, determined crystallographic constants, and did research on ketone and aldehyde compounds. |
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The effect of clouds on clear air photolysis rate constants was included through multiplication by a correction factor according to the method described by Chang et al. |
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In 1749 he went on to explain that if several normal mode solutions of the wave equation are superposed, the result is a solution of the form where the coefficients a1, a2, a3, … are arbitrary constants. |
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Western science makes extrapolations to the past based upon precise but short-period measurements and observations, and is suspicious about projecting into the future except for physical constants and processes. |
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The size of these constants is linked with the size of the constructed finite automata, that in turn depends mainly on the quantifier depth of formulas. |
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Isotopes of an element may have slightly different equilibrium constants for a particular chemical reaction, so that slightly different amounts of reaction products are made from reactants containing different isotopes. |
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A critical factor in the use of Bernoulli distributions is that the parameters of the distribution are known constants. |
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This is because a requirement for any future definition of the unit of mass based on atomic or fundamental constants is a long-term commitment to monitoring the mass of present artefact, the International Prototype. |
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In consequence, predictions using these constants are less accurate for minuscule samples of atoms. |
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For precise calculations, errors due to rounding and the number of significant digits of constants must be considered. |
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The correlation between reaction rate constants and activation energy can be obtained using Arrhenius equation. |
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The only constants in the five lineups so far have been Darin Erstad batting leadoff, Vladimir Guerrero hitting third and Garret Anderson fourth. |
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Spell-check your Visual Studio files and easily correct those embarrassing spelling mistakes in comments, XML documents, string constants, and HTML files. |
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This supermodulation has a periodicity nearly commensurate with four lattice constants in-plane, eight out-of-plane, with long correlation lengths in three dimensions. |
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The calculation of hydrogen ion concentrations, using this formalism, is a key element in the determination of equilibrium constants by potentiometric titration. |
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This leads to a mixing in molecular spectra between the rotational and vibrational levels, from which Coriolis coupling constants can be determined. |
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These estimated values included g-factors, hyperfine structure constants, and line widths that characterized the shape and intensity of each spectral component. |
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Testing for the constancy of the fundamental constants has proven to be an efficient test of Einstein equivalence principle that can be performed on astrophysical scales. |
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Monocrystal and polycrystal elastic constants of titanium diboride. |
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Relaxor ferroelectrics exhibit useful physical properties, such as a high dielectric constant over a wide range of temperature and large electromechanical coupling constants. |
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The app includes a glossary of more than 300 technical corrosion engineering terms, a list of constants, such as the Boltzmann constant, reference electrodes and schematics. |
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