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What is an autoionization?

What is an autoionization? Here are some definitions.

Noun
  1. A process by which atoms or molecules spontaneously transition from an electrically neutral state to a lower-energy ionized state
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Examples
The model included the effects of changing activity and the autoionization of water.
This is known as the Auger effect or autoionization since the ion has self-ionized after the photoionization event.

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