Perhaps the richest and certainly the most extensively studied cluster compounds are the carbonyl complexes. |
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We investigated a role of the glyoxalase detoxification system of precursor reactive carbonyl compounds in the in vivo AGE formation. |
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In this process carbonyl compounds form hydrates which have different properties from those of the parent. |
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In simple additions, the carbonyl compounds can behave as both Lewis acids and Lewis bases depending on what reagents are present. |
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On the other hand, the weak site has a quadrangular pyramidal structure with three peptide carbonyl groups and two water molecules. |
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It includes the glycerol and carbonyl groups and the hydrocarbon chains of the lipid. |
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This reaction occurs between an ylide and a carbonyl group which ultimately yields the alkene. |
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The carboxylic acid group of the drug is first reacted with an activated carbonyl group like that found on isobutyl chloroformate. |
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Oxidation of an aldehyde breaks the double bond within the carbonyl group to give a carboxylic acid. |
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As a result, carbonyl compounds can form carbon anions and act as nucleophiles rather than electrophiles. |
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The reaction of Grignard reagents with carbonyl compounds is used to prepare primary, secondary, and tertiary alcohols. |
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The carboxyl group can also be converted into an alcohol by reduction of the carbonyl carbon. |
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It is known that metal cations form complexes with anionic phosphodiester groups and carbonyl oxygens in the glycerol backbone of phosphocholine lipids. |
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The result is a slight displacement of the imide hydrogen toward the oxygen atom of the carbonyl group. |
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A flake shaped iron pigment, characterized in that it is produced from reductively treated carbonyl iron powder. |
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In the case of aldehydes and ketones containing carbonyl groups, the highly nucleophilic Grignard reagent contributes its electron pair to form a bond with the carbon atom. |
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The carbon atom of a carbonyl group is bonded to two other atoms in addition to the oxygen atom. |
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Reduced sulphur gases such as hydrogen sulphide, carbon disulphide and carbonyl sulphide from natural and anthropogenic sources. |
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Carbon monoxide and the crude nickel react to form nickel carbonyl at high pressure. |
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Incinerators should be used to convert the nickel carbonyl to nickel oxide and carbon dioxide. |
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Vapo-metallurgical technologies such as Inco Carbonyl Process whereby nickel alloys are treated with carbon monoxide gas to form nickel carbonyl. |
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The trigonal planar arrangement of the groups around the carbonyl carbon atom enables the carbon atom to be relatively open to attack from above, or below. |
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Like phosgene and diphosgene, which share a characteristic odor of freshly-cut grass, carbonyl chloride was potentially available for use in the war. |
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Sulfur-containing compounds can interact with carbonyl compounds to produce a livery flavor. |
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The carbonyl ligands in the tetracarbonylnickel molecule project toward the vertices of a tetrahedron, and thus the structure is referred to as tetrahedral. |
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To refine impure nickel, alloys are treated with carbon monoxide gas to form nickel carbonyl gas, which is later separated into nickel metal powder and carbon monoxide gas. |
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Grignard reagents react with carbonyl groups to secondary and tertiary alcohols. |
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The classes represented in this collection include inorganic compounds, inorganic coordination compounds, organic coordination compounds, metal carbonyl compounds, and boranes. |
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Hydroperoxide initiate autoxidation of lipid by attacking on the double bond in fatty acids and subsequently produce carbonyl compounds. |
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It can be distinguished from other ambers via IR spectroscopy due to a specific carbonyl absorption peak. |
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The papers represent the latest research in aldehyde dehydrogenases, alcohol dehydrogenases, carbonyl reductases. |
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In the alpha helix there is hydrogen bonding between the hydrogen on the nitrogen and the oxygen on the carbonyl carbon within the same sheet. |
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The investment plans for the Severonickel Combine include optimization of the carbonyl nickel powder production, increased copper output, and increased recycling. |
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The applicability of CEC using a commercially available CE system with photodiode array detection and a 3 Fm porous C18-bonded silica capillary column for analysing carbonyl hydrazones was studied. |
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Hydride transfer reagents, such as NaBH4 and LiAlH4, are widely used in organic chemistry, primarily in the reduction of carbonyl compounds to alcohols. |
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The authors cover general principles of this scientific discipline such as macrocyclic stereocontrol, chiral acetals, conjugate additions and carbonyl addition reactions. |
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The enolization ability of the carbonyl group is well known. |
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The first chapter reviews basic carbohydrate chemistry including carbonyl, carboxyl, and hydroxyl modifications, glycosidic linkages, and polymerization. |
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The method claimed for imparting nonvolatility to the smelly aldehydes was the facile reaction of the carbonyl groups thereof with primary amines to form imines. |
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The antimicrobial impact of cinnamaldehyde in suggested to arise through its carbonyl group interaction with proteins in the periplasm and inactivation microbial enzymes. |
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One theory about this outcome speculates that carbonyl groups in the sugar molecules created an immediate antidote by reacting with the poison cyanide to form cyanohydrins. |
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