| The role of the isoalloxazine coating is proposed to be surface passivation from molecular oxygen. |
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| Flavins are arguably one of the most versatile cofactors by virtue of the reactivity of the isoalloxazine ring system. |
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| In Anabaena Flavodoxin both the protein environment and the redox state contribute to modulate the chemical reactivity of the isoalloxazine ring. |
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| This suggests that the isoalloxazine moiety is sufficient for catalysis. |
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| Stronger interactions between the isoalloxazine and nicotinamide rings might relate with faster HT processes, but exceptions are found upon distortion of the active centre. |
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| Flavine adenine dinucleotide exhibits fluorescence due to its isoalloxazine conjugated ring structure. |
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